Search results for "quantum [effect]"
showing 10 items of 5105 documents
1H and 13C HR-MAS spectroscopy of intact biopsy samples ex vivo and in vivo 1H MRS study of human high grade gliomas.
2004
High-resolution magic angle spinning (HR-MAS) one- and two-dimensional 1H and 13C nuclear magnetic resonance (NMR) spectroscopy has been used to study intact glioblastoma (GBM) brain tumour tissue. The results were compared with in vitro chemical extract and in vivo spectra. The resolution of 1H one-dimensional, 1H TOCSY and 13C HSQC HR-MAS spectra is comparable to that obtained on perchloric extracts. 13C HSQC HR-MAS spectra have been particularly useful for the identification of 37 different metabolites in intact biopsy tumours, excluding water and DSS components. To our knowledge, this is the most detailed assignment of biochemical compounds obtained in intact human tissue, in particular…
Studies of Quantum Chromodynamics with the ALEPH Detector
1998
Previously published and as vet unpublished QCD results obtained with the ALEPH detector at LEP1 are presented. The unprecedented statistics allows detailed studies of both perturbative and non-perturbative aspects of strong interactions to be carried out using hadronic Z and tau decays. The studies presented include precise determinations of the strong coupling constant. tests of its flavour independence, tests of the SU(3) gauge structure of QCD, study of coherence effects, and measurements of single-particle inclusive distributions and two-particle correlations for many identified baryons and mesons. (C) 1998 Elsevier Science B.V.
Multi-letter reversible and quantum finite automata
2007
The regular language (a+b)*a (the words in alphabet {a, b} having a as the last letter) is at the moment a classical example of a language not recognizable by a one-way quantum finite automaton (QFA). Up to now, there have been introduced many different models of QFAs, with increasing capabilities, but none of them can cope with this language. We introduce a new, quite simple modification of the QFA model (actually even a deterministic reversible FA model) which is able to recognize this language. We also completely characterise the set of languages recognizable by the new model FAs, by finding a "forbidden construction" whose presence or absence in the minimal deterministic (not necessaril…
Numerical evaluation of multiple polylogarithms
2004
Multiple polylogarithms appear in analytic calculations of higher order corrections in quantum field theory. In this article we study the numerical evaluation of multiple polylogarithms. We provide algorithms, which allow the evaluation for arbitrary complex arguments and without any restriction on the weight. We have implemented these algorithms with arbitrary precision arithmetic in C++ within the GiNaC framework.
The Dynamical Problem for a Non Self-adjoint Hamiltonian
2012
After a compact overview of the standard mathematical presentations of the formalism of quantum mechanics using the language of C*- algebras and/or the language of Hilbert spaces we turn attention to the possible use of the language of Krein spaces.I n the context of the so-called three-Hilbert-space scenario involving the so-called PT-symmetric or quasi- Hermitian quantum models a few recent results are reviewed from this point of view, with particular focus on the quantum dynamics in the Schrodinger and Heisenberg representations.
Algebraic Results on Quantum Automata
2004
We use tools from the algebraic theory of automata to investigate the class of languages recognized by two models of Quantum Finite Automata (QFA): Brodsky and Pippenger’s end-decisive model, and a new QFA model whose definition is motivated by implementations of quantum computers using nucleo-magnetic resonance (NMR). In particular, we are interested in the new model since nucleo-magnetic resonance was used to construct the most powerful physical quantum machine to date. We give a complete characterization of the languages recognized by the new model and by Boolean combinations of the Brodsky-Pippenger model. Our results show a striking similarity in the class of languages recognized by th…
Electronic excitations of 1,4-disilyl-substituted 1,4-disilabicycloalkanes: a MS-CASPT2 study of the influence of cage size.
2007
We present a multistate complete active space second-order perturbation theory computational study aimed to predict the low-lying electronic excitations of four compounds that can be viewed as two disilane units connected through alkane bridges in a bicyclic cage. The analysis has focused on 1,4-disilyl-1,4-disilabicyclo[2.2.1]heptane (1a), 1,4-bis(trimethylsilyl)-1,4-disilabicyclo[2.2.1]heptane (1b), 1,4-disilyl-1,4-disilabicyclo[2.1.1]hexane (2a), and 1,4-bis(trimethylsilyl)-1,4-disilabicyclo[2.1.1]hexane (2b). The aim has been to find out the nature of the lowest excitations with significant oscillator strengths and to investigate how the cage size affects the excitation energies and the…
Supramolecular Aggregates in Vacuum: Positively Mono-Charged Sodium Alkanesulfonate Clusters
2010
The formation and structural features of positively mono-charged aggregates of sodium bis(2-ethylhexyl) sulfosuccinate (AOT) and sodium methane—(MetS), butane—(ButS) and octane—(OctS) sulfonate molecules in the gas phase have been investigated by electrospray ionization mass spectrometry, energy-resolved mass spectrometry and density functional theory (DFT) calculations. The experimental results show that the center-of-mass collision energy required to dissociate 50% of these mono-charged aggregates scantly depends on the length of the alkyl chain as well as on the aggregation number. This, together with the large predominance of mono-charged species in the mass spectra, was rationalized i…
Unsaturated syn- and anti-1,2-Amino Alcohols by Cyclization of Allylic Bis-trichloroacetimidates. Stereoselectivity Dependence on Substrate Configura…
2014
Disubstituted allylic bis-imidates undergo Lewis acid catalyzed or spontaneous cyclization to oxazolines, which are precursors of unsaturated amino alcohols. Stereoselectivity of the cyclization is mainly determined by the substrate configuration. Highly selective cis-oxazoline formation is achieved starting from anti-E-bis-imidates while trans-oxazoline predominantly forms from anti-Z-bis-imidates. On the basis of DFT calculations, the stereoselectivity trends can be explained by the formation of the energetically most stable carbenium ion conformation, followed by the cyclization via most favorable bond rotations.
Properties of native ultrathin aluminium oxide tunnel barriers
2003
We have investigated planar metal–insulator–metal tunnel junctions with aluminium oxide as the dielectricum. These oxide barriers were grown on an aluminium electrode in pure oxygen at room temperature till saturation. By applying the Simmons model we derived discrete widths of the tunnelling barrier, separated by Δs ≈ 0.38 nm. This corresponds to the addition of single layers of oxygen atoms. The minimum thickness of s0 ≈ 0.54 nm is then due to a double layer of oxygen. We found a strong and systematic dependence of the barrier height on the barrier thickness. Breakdown fields up to 5 GV m−1 were reached. They decreased strongly with increasing barrier thickness. Electrical breakdown could…